<asp:DropDownList ID="DropDownList1" runat="server" AppendDataBoundItems="true">
<asp:ListItem Text="Select Value" Value="0"></asp:ListItem>
</asp:DropDownList>
<asp:RequiredFieldValidator id="RequiredFieldValidator2" runat="server" ControlToValidate="DropDownList1" InitialValue="Select Value" ErrorMessage="Select Value required." ForeColor="Red"></asp:RequiredFieldValidator>
asp:DropDownList is displaying static value (Select Value) and dynamic value from database.
Go to the complete details ...